Properties of H2S
Colour: Colourless (Invisible.)
Odour commonly referred to as odour of rotten eggs
Vapour density 1.189 (Air=1.0) H2S is heavier than air
Explosive limits Highly explosive. (4.3 to 46.) Percent by volume in air
Auto ignition temp. 260 degrees C
Flammability Forms explosive mixture with air or oxygen
Water solubility 2.9 percent (2.9g/100 ml water at 20 degrees C
Can destroy steel and rubber seals very quickly.
Effects of H2S
10,000 parts
per million = 1 percent
1 ppm: Can be smelled. or to put it
another way, 1 second in 13 days. Not a lot of room for error.
10 ppm: Occupational Exposure Limit, for 8 hours: At very low
concentrations of less than 10-100 ppm, it gives off unpleasant odour -
like to rotten eggs. "the threshold limit".
15 ppm: Occupational Exposure Limit, allowable for 15 minutes of
exposure.
20 ppm: Occupational Exposure Limit, At this level workers must wear
appropriate breathing apparatus.
The limits here are set in Canada and
conform very much to many other countries
100 ppm: the gas kills the sense of smell in 3-15 minutes and will cause
you to cough or your eyes to water, possible headache, nausea, throat
irritation.
Note~ Smell is only a temporary
warning. Do not rely on your nose.
200 ppm: your eyes and throat will begin to burn. and you will get
Headaches. Sense of smell lost rapidly.
300 ppm: Immediately Dangerous to Life and Health level. Positive
pressure breathing apparatus required.
500 ppm: Loss of reasoning and balance. Respiratory disturbances in 2 to
15 minutes.
700 ppm: Immediate unconsciousness. Death will result if not rescued ASP.
1000 ppm: Immediate unconsciousness. Causes seizures, loss of control of
bowel and bladder. Breathing will stop and death will result if not
rescued promptly. Immediate resuscitation needed.
Comparison of H2S with other lethal gasses will help you to understand
the importance why (a you can not work alone (b the reason for prompt and
swift action. H2S has a threshold limit of 20 ppm and a lethal
concentration of 600 ppm.
Hydrogen cyanide (used in gas chambers) has a threshold limit of 10 ppm
and a lethal concentration of 300 ppm.
Carbon monoxide (CO) has a threshold limit of 50 ppm and a lethal
concentration of 1,000 ppm.
You should by now be getting the picture and an understanding of why so
much preparation and precautions need to be taken before any attempt is
made to drill or workover a well that expects to encounter H2s.
Over the following pages we will put together some useful information
that will show you that it can be drilled and drilled safely providing
you respect and follow the rules.
When using the term "the threshold limit". This is the
concentration at which it is believed you may be repeatedly exposed, day
after day, without adverse affects.