Hydrogen sulphide gas
Hydrogen sulphide gas
is one of the most deadly occupational hazards in
drilling. It goes by many names: H2S, Sour Gas and
Sulfuretted Hydrogen.
People working in the oil and gas industry must be
aware of its deadly properties. Sewer maintenance
crews, blasters and miners have learned to respect
this gas.
Employers must ensure that workers who may be
exposed to H2S gas are able to recognize its lethal
effects. Workers should also know how to rescue and
administer first aid to victims who are overcome.
The purpose of this section of the site is to alert
employers to the dangers involved in working with
H2S and to provide guidance for controlling those
dangers and to give confidence while working in
affected areas such as the Far and Middle East and
parts of Canada
The objective of this site is not to teach old dogs new tricks, most major
operator are well familiar with the dangers of H2s and have all there plans in place.
The industry is changing. Over the past 12 years I have worked for many
small indigenous companies. Many
are new to the oil industry and some have much to learn.
It is our responsibility
to continue to train others. Hydrogen-sulphide (H2s) is a gas encountered all
over the world. Drilling formations with the presence of H2S can
encounter some very serious problems.
This section we will attempt to
cover the characteristics, detection, prevention,
emergency procedures, safety and first aid, and
training and planning. Due to the serious nature of
this gas, coupled with fear and sometimes
disrespect. We will attempt to get a clear
understanding.
Introduction
However before starting I will tell a short but true story.
Some years back "Not that many" we were drilling a known H2s area. After tripping for the
bit, drilling continued. As one would expect bottoms up eventually came to surface, along with it came
a lot of H2s. Constant drills had taught everybody to masks up at the first indication and of course
this was done.
However not everyone understood what was going on. From the time the rotary stopped turning until
the time the rig was secure, the rig floor telephone never stopped ringing. Once I answer it, I cant
understand a word your saying take your mask "off" A slip up such as that could cost a
person their life.
I have never believe in the Dog eat Dog attitude or the F*** U Jack I'm all right approach. But
under H2s conditions It MUST be the attitude you take. As much as I hate to say it. If your best friend
is laying out there. You do not go and assist until you are masked up.
TERMINOLOGY
PPM means ( Parts Per Million) and is used for the
so-called toxic gases such as Hydrogen Sulphide and
Carbon Monoxide.
These two gases require separate sensors because
their lethal concentrations are so different - H2S
is deemed dangerous above 10ppm (UK) or 15 ppm (US)
whilst CO may be survivable at over 200ppm although
most monitors will alarm at only 35ppm (US) 50ppm
(UK).
It is surprising to many to learn that a
fundamental gas like methane will not explode in
the presence of a flame until it reaches a very
specific concentration - below a certain level the
gas is deemed too lean to burn and above a certain
limit the gas may be too rich to burn rather like
smothering a fire with too much wood.
But within what may be a narrow band, between the
Lower Explosive Limit (LEL) and the Upper Explosive
Limit (UEL) such gases will ignite with only the
faintest whiff of a Zippo.
Other gas related terms are:
TLV: (Threshold Limit Value) & TWA (Time Weighted
Average) both are referring to the duration of
exposure to a particular atmosphere. TWA usually
refers to an 8 hour working day over a 40 hour
week. TLV will include this definition but also
defines two other exposure limits - Short term or
15minute exposure and an absolute limit or ceiling
which is the most that an individual should ever be
exposed to.
PEL is the (Permissible Exposure Limit) and this is
a figure defined by the OSHA (US equivalent of HSE
in the UK) as the legal limit of exposure for an
employee. This means that they may be knowingly
exposed to a known hazardous gas for no longer than
a legislated maximum time. Any exposure beyond the
PEL for that particular gas and the bereaved
relatives can presumably sue.
STEL: is a UK term meaning (Short Term Exposure
Limit) and refers to a maximum concentration or
percentage exposure over a 15 minute period
(similar to TLV-Short Term above)
IDLH means (Immediately Dangerous to Life or
Health) and is not something you want to see next
to a low number on a Permit before making an entry.
This is because IDLH given as a percentage or PPM
represents the maximum exposure level at which you
could survive for 30 minutes without breathing
apparatus and without incurring debilitating
symptoms which would hinder your escape or even
irreversibly damage your health. Thus if a gas is
given an IDLH of 1ppm or .000001% you know that
it's a nasty one and if your SCBA packs up when
your monitor is showing 10ppm its Goodnight Vienna. |